Why asymptotic limit of the acid dissolution capacity can lead to a sharp dissolution front in chemical dissolution of porous rocks?          下载免费PDF全文

Chongbin Zhao  B.E. Hobbs  A. Ord 《国际地质力学数值与分析法杂志》2017,41(15):1590-1602

The use of the asymptotic limit can greatly simplify the theoretical analysis of chemical dissolution front instabilities in fluid‐saturated rocks and therefore make it possible to obtain mathematical solutions, which often play a crucial role in understanding the propagation behavior of chemical dissolution fronts in chemical dissolution systems. However, there has been a debate in recent years that the asymptotic limit of the acid dissolution capacity (i.e., the acid dissolution capacity number approaching zero) alone cannot lead to a sharp dissolution front of the Stefan type in the acidization dissolution system, in which the dissolvable minerals of carbonate rocks are chemically dissolved by the injected acid flow. The acid dissolution capacity number is commonly defined as the ratio of the volume of the carbonate rock dissolved by an acid to that of the acid. In this paper, we use four different proof methods, including (i) direct use of the fundamental concepts; (ii) use of the mathematical governing equations of an acidization dissolution system; (iii) use of the different time scaling approach; and (iv) use of a moving coordinate system approach, to demonstrate that the asymptotic limit of the acid dissolution capacity can indeed lead to sharp dissolution fronts of the Stefan type in acidization dissolution systems on a much larger time scale (than the dissolution time scale). Our new finding is that on the reaction time scale, the condition of the conventional time derivative of porosity approaching zero alone can ensure that the acidization dissolution front has a sharp shape of the Stefan type. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Variational analysis of dynamics of fissured poroelastic rocks     

《Soil Dynamics and Earthquake Engineering》2016

Rocks can be modeled in a continuum framework as fissured, poroelastic materials, i.e., materials with two degrees of porosity, one due to the fissures and another one due to the pores. The governing equations of motion of fissured poroelastic rocks established by Beskos are rederived here by establishing a variational statement which also provides the boundary conditions of the problem. This is accomplished by considering strain, dissipation and kinetic energies as well as the work of external forces. The above statement is also derived here by employing the method of weighted residuals.  相似文献   

Lower crustal melting via magma underplating: Elemental and Sr–Nd–Pb isotopic constraints from late Mesozoic intermediate–felsic volcanic rocks in the northeastern North China Block     

CHAOWEN LI  FENG GUO  WEIMING FAN 《Island Arc》2011,20(4):477-499

Ar–Ar dating, major and trace element analyses, and Sr–Nd–Pb isotope results of two groups of Lower Cretaceous (erupted at 126 and 119 Ma, respectively) intermediate–felsic lava from the northeastern North China Block (NCB) suggest their derivation from melting of mixtures between the heterogeneous lower crust and underplated basalts. Both groups exhibit high‐K calc‐alkaline to shoshonitic affinities, characterized by light rare earth element (LREE) and large ion lithophile element (LILE) enrichment and variable high field strength element (HFSE, e.g. Nb, Ta and Ti) depletion, and moderately radiogenic Sr and unradiogenic Nd and Pb isotopic compositions. Compared with Group 2, Group 1 rocks have relatively higher K₂O and Al₂O₃/(CaO + K₂O + Na₂O) in molar ratio, higher HFSE concentrations and lower Nb/Ta ratios, and higher Sr–Nd–Pb isotope ratios. Group 1 rocks were derived from a mixture of an enriched mantle‐derived magma and a lower crust that has developed radiogenic Sr and unradiogenic Nd and Pb isotopic compositions, whereas the Group 2 magmas were melts of another mixture between the same mantle‐derived component and another type of lower crust having even lower Sr, Nd, and Pb isotopic ratios. Shift in source region from Group 1 to Group 2 coincided with a change in melting conditions: hydrous melting of both the underplated basalt and the lower crust produced the earlier high‐Nb and low‐Nb/Ta melts with little or no residual Ti‐rich phases; while the younger low‐Nb and high‐Nb/Ta magmas were melted under a water‐deficient system, in which Ti‐rich phases were retained in the source. Generation of the two groups of intermediate–felsic volcanic rocks was genetically linked with the contemporaneous magma underplating event as a result of lithospheric thinning in the eastern NCB.  相似文献   

火山岩风化体储层控制因素研究—以三塘湖盆地石炭系卡拉岗组为例   总被引：4，自引：0，他引：4       下载免费PDF全文

侯连华 《地质学报》2011,85(4):557-568

针对火山岩风化壳储层控制因素和成因复杂的难题,以三塘湖盆地石炭系卡拉岗组为例,在搞清晚石炭世构造环境和岩性特征基础上,提出风化淋滤和断裂改造是火山岩风化壳形成有利储层的主要控制因素.不同火山岩岩性经风化淋滤后储层物性均增大并能形成有利储层,储集层孔隙类型以次生溶蚀孔隙和裂缝为主,具双峰分布特征.建立了5层结构模型,并提...  相似文献   

Cenozoic temperate and sub‐tropical carbonate sedimentation on an oceanic volcano – Chatham Islands,New Zealand     

NOEL P. JAMES  BRIAN JONES  CAMPBELL S. NELSON  HAMISH J. CAMPBELL  JEREMY TITJEN 《Sedimentology》2011,58(4):1007-1029

The Chatham Islands, at the eastern end of the Chatham Rise in the South‐west Pacific, are the emergent part of a Late Cretaceous to Cenozoic stratovolcano complex that is variably covered with limestones and fossiliferous tuffs. Most of these deposits accumulated in relatively shallow, high‐energy, tide‐influenced palaeoenvironments with deposition punctuated by periods of deeper‐water pelagic accumulation. Carbonate components in these neritic deposits are biogenic and dominated by molluscs and bryozoans – a heterozoan assemblage. The widespread Middle to Late Eocene Matanginui Limestone contains local photozoan elements such as large benthonic foraminifera (especially Asterocyclina) and calcareous green algae, reflecting the general Palaeogene sub‐tropical oceanographic setting. More localized Late Eocene to Oligocene deposits (Te One Limestone) as well as Pliocene carbonates (Onoua Limestone) are, however, wholly heterozoan and confirm a generally cooler‐water oceanographic setting, similar to today. Early sea floor diagenesis is interpreted to have removed most aragonite components (infaunal bivalves and epifaunal gastropods). Lack of aragonite resulted in the absence of intergranular calcite cementation during subaerial exposure, such that most carbonates are friable or unlithified. Cementation is, however, present at nodular hardground–firmground caps to metre‐scale cycles. Such cements are microcrystalline or micrometre‐thick isopachous circumgranular rinds with insufficient definitive attributes to pinpoint their environment of formation. The overall palaeoenvironment of deposition is interpreted as mesotrophic, resulting in part from upwelling about the Chatham volcanic massif and in part from nutrient element delivery from the adjacent volcanic terrane and coeval volcanism. Biotic diversity in tuffs is two to three times that in limestones, supporting the notion of especially high nutrient availability during periods of volcanism. These mid‐latitude deposits are strikingly different from their low‐latitude, tropical, photozoan counterparts in the volcanic island–coral reef ecosystem. Ground water seepage and fluvial runoff attenuate coral growth and promote microbial carbonate precipitation in these warm‐water settings. In contrast, nutrients from the same sources feed the system in the Chatham Islands cool‐water setting, promoting active heterozoan carbonate sedimentation.  相似文献   

深圳大鹏半岛国家地质公园中生代火山地层的时代讨论     

梅村  唐跃林  张崧  康镇江  管福贞  龚淑云  李甘 《地层学杂志》2011,(4):454-462

深圳地区中生代火山地层分布区是我国东南沿海浙闽粤港火山活动带的一个重要组成部分,是我国沿海地区侏罗纪—白垩纪火山地层较有代表性地段,也是研究我国东南沿海侏罗纪—白垩纪火山活动的天然博物馆。近期通过野外观察,测制火山地层剖面,进行锆石同位素激光定年测试,对大鹏半岛国家地质公园中生代火山地层的时代提出新的认识,将原划分为上侏罗统高基坪群划分为早—中侏罗世塘厦组(181.8 Ma?)、中侏罗世吉岭湾组(165.8 Ma)、晚侏罗世梧桐山组(156.9~145.6 Ma)、晚侏罗世—早白垩世七娘山组(146.3~131.0 Ma)、早白垩世官草湖群等。  相似文献   

班公湖-怒江缝合带西段改则硅质岩地球化学征及沉积环境   总被引：5，自引：0，他引：5  

冯彩霞 《矿床地质》2011,30(5):773-786

班公湖-怒江缝合带是西藏第二条规模巨大的基性-超基性岩带.文章通过对该带西段改则地区硅质岩的系统地球化学研究,探讨了硅质岩形成的成因和构造背景.研究表明:①硅质岩的w(SiO2)变化范围在85.23％～93.73％之间,Si/Al比值为34.08～56.92,表明它们含有较高比例的陆源泥质沉积物;②Hf、Pb、Nb、T...  相似文献   

贝尔凹陷“源断势”对油成藏与分布的控制作用          下载免费PDF全文

付广  刘云燕 《地质科学》2011,46(4):1068-1078

为了研究贝尔凹陷源岩、断裂和势能场(简称“源断势”)控藏模式,采用油藏分布与源、断、势叠合方法,分别对油成藏、分布控制作用和控藏模式进行了研究,结果得到:1)南一段油源区控制着油藏形成与分布的范围;2)低势区控制着油聚集的部位;反向断裂翘倾隆起的低势区控制着南屯组和铜钵庙组油聚集成藏,反转构造低势区控制着大磨拐河组油聚...  相似文献   

东营凹陷古近系升藿烷生物标志物参数分布及演变规律     

陈中红  查明  金强  任拥军 《沉积学报》2011,29(1):173-183

为研究实际地质体或地质剖面中的C31到C3517α(H), 21β(H)升藿烷生物标志物构型转化参数22S/(22S+22R)及升藿烷指数C35/∑（C31—C35)等的分布、演化特征,对东营凹陷主要烃源岩层系古近系沙河街组三段（淡水—微咸水层系）和沙河街组四段（咸水层系）的系列样品进行了研究,分析样品来源于1 300~4 000的暗色泥岩,其中2 800~4 000 m的样品对应于东营凹陷古近系烃源岩的生油初期到生油晚期。研究结果表明,C31、C32、C33、C34、C35升藿烷（17α(H), 21β(H)）构型转化参数的分布除与异构体之间的手性碳立体构型转化作用有关外,不同异构体之间降解或裂解速率和新生成速率的差异也是其主要控制因素,沉积环境（如高盐环境）也在一定程度上影响了其分布;从未熟—低熟状态到成熟状态,相关升藿烷构型转化参数22S/(22S+22R)总体均表现出随埋藏深度增大而加大的特点,并从离散状态聚集到热演化的平衡状态附近;在到达成熟状态后,相关升藿烷的构型转化参数22S/(22S+22R)从缓慢增大过渡到一个持续的热演化平衡状态,并且该构型转化参数的热演化平衡状态对应于生油门限附近;在高盐环境中除C33升藿烷保持不变的热演化平衡状态外,其它升藿烷均呈现不同幅度的逆转特征,表明高含量的盐类矿物对升藿烷成熟度参数亦具有抑制作用或迟缓效应;C31、C32、C33、C34、C3517α升藿烷之间的22S/(22S+22R)分布型式复杂多变,其中对于成熟源岩样品,C35升藿烷22S/(22S+22R)值变化强烈,表现出“翘尾”状的上升型特征和“坠尾”状的下降型特征,而对于低熟—未熟样品, C32升藿烷的22S/(22S+22R)显示相对高值,并且多数样品显示为C31C33C35的偶数碳优势的特征;研究显示C31到C33升藿烷的构型转化参数S/(S+R)热演化平衡值均为0.6,而C34 S/(S+R)及C35S/(S+R)热演化平衡值相对较高,沙三段、沙四段的C34 S/(S+R)及沙四段的C35S/(S+R)分别达到0.63、0.62、0.65;升藿烷指数C35/∑（C31—C35)受热演化影响也比较明显,在生油期间随着埋藏深度增加而减小,在高盐环境中表现出相对高值,研究表明该指数的变化与其22R异构体演化有关,并且参数C31/∑（C31—C35）、C32/∑（C31—C35）、C33/∑（C31—C35）、C34/∑（C31—C35）、C35/∑（C31—C35)演化特征截然不同。  相似文献   

全球变化背景下新疆地区气候跃变的可能影响因素分析   总被引：1，自引：0，他引：1  

李稚  李卫红  陈亚宁 《冰川冻土》2011,33(6):1302-1309

基于新疆过去50a气温和降水时间序列长期趋势的研究结果,结合对1986年及附近时段对全球气候产生重大影响的一系列事件（厄尔尼诺、火山爆发、核电站爆炸事故、温室气体增加等）的分析,探讨了1986年新疆气温和降水出现跳跃式变化的原因.具体表现为：当厄尔尼诺现象发生时,常常出现暖冬、早春,在该现象消退过程,往往降水有所增多;...  相似文献